Stabilizing Magnesium Hydride Complexes with Neutral Ligands
نویسندگان
چکیده
منابع مشابه
Niobium tetrahalide complexes with neutral diphosphine ligands.
The reactions of NbCl4 with diphosphine ligands o-C6H4(PMe2)2, Me2PCH2CH2PMe2 or Et2PCH2CH2PEt2 in a 1 : 2 molar ratio in MeCN solution produced eight-coordinate [NbCl4(diphosphine)2]. [NbBr4(diphosphine)2] (diphosphine = o-C6H4(PMe2)2 or Me2PCH2CH2PMe2) were made similarly from NbBr4. X-ray crystal structures show that [NbCl4{o-C6H4(PMe2)2}2] has a dodecahedral geometry, but the complexes with...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2019
ISSN: 1434-1948,1099-0682
DOI: 10.1002/ejic.201900936